TSEAMCET 2022 Expected Syllabus
30% Deleted Syllabus is given below in RED Colour
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CHEMISTRY
1) ATOMIC STRUCTURE: Introduction; Sub- atomic particles; Atomic models – Thomson’s Model; Rutherford’s Nuclear model of atom, Drawbacks; Developments to the Bohr’s model of atom; Nature of electromagnetic radiation; Particle nature of electromagnetic radiation- Planck’s quantum theory; Bohr’s model for Hydrogen atom; Explanation of line spectrum of hydrogen; Limitations of Bohr’s model; Quantum mechanical considerations of sub atomic particles; Dual behaviour of matter; Heisenberg’s uncertainty principle; Quantum mechanical model of an atom. Important features of Quantum mechanical model of atom; Orbitals and quantum numbers; Shapes of atomic orbitals; Energies of orbitals; Filling of orbitals in atoms. Aufbau Principle, Pauli’s exclusion Principle and Hund’s rule of maximum multiplicity; Electronic configurations of atoms; Stability of half filled and completely filled orbitals.
2)
CLASSIFICATION OF ELEMENTS AND
PERIODICITY IN PROPERTIES: Need to classify elements; Genesis of periodic
classification; Modern periodic law and present form of the periodic table;
Nomenclature of elements with atomic number greater than 100; Electronic configuration
of elements and the periodic table; Electronic configuration and types of
elements s, p, d and f blocks; Trends in physical properties: (a) Atomic
radius, (b) Ionic radius (c) Variation of size in inner transition elements,
(d) Ionization enthalpy, (e) Electron gain enthalpy, (f) Electro negativity;
Periodic trends in chemical properties: (a) Valence or Oxidation states, (b)
Anomalous properties of second period elements - diagonal relationship;
Periodic trends and chemical reactivity.
3)
CHEMICAL BONDING AND MOLECULAR
STRUCTURE: Kossel - Lewis approach to chemical bonding, Octet rule,
Representation of simple molecules, formal charges, limitations of octet rule;
Ionic or electrovalent bond - Factors favorable for the formation of ionic
compounds-Crystal structure of sodium chloride, Lattice enthalpy; General
properties of ionic compounds; Bond Parameters - bond length, bond angle, bond enthalpy, bond order, resonance -
Polarity of bonds dipole moment; Valence Shell Electron Pair Repulsion (VSEPR)
theory; Predicting the geometry of simple molecules; Valence bond
theory-Orbital overlap concept-Directional properties of bonds-overlapping of
atomic orbitals, strength of sigma
and pi bonds-Factors favouring the formation of covalent bonds; Hybridisation-
different types of hybridization involving s, p and d orbitals- shapes of
simple covalent molecules; Coordinate bond -definition with examples; Molecular
orbital theory - Formation of molecular orbitals, Linear combination of atomic
orbitals (LCAO)-conditions for combination of atomic orbitals - Energy level diagrams for molecular orbitals
-Bonding in some homo nuclear diatomic molecules- H2, He2,
Li2, B2, C2, N2 and O2;
Hydrogen bonding-cause of formation of hydrogen bond - Types of hydrogen
bonds-inter and intra molecular-General properties of hydrogen bonds.
4)
STATES OF MATTER: GASES AND LIQUIDS:
Intermolecular forces; Thermal Energy; Intermolecular forces vs Thermal
interactions; The Gaseous State; The Gas Laws; Ideal gas equation; Graham’s law
of diffusion - Dalton’s Law of partial pressures; Kinetic molecular theory of
gases; Kinetic gas equation of an ideal gas (No derivation); deduction of gas
laws from Kinetic gas equation; Distribution of molecular speeds - rms, average
and most probable speeds-Kinetic energy of gas molecules; Behaviour of real
gases - Deviation from Ideal gas behaviour - Compressibility factor vs Pressure
diagrams of real gases; Liquefaction of gases; Liquid State - Properties of
Liquids in terms of Inter molecular interactions - Vapour pressure, Viscosity
and Surface tension (Qualitative idea only. No mathematical derivation).
5)
STOICHIOMETRY: Some basic concepts - Properties of matter - uncertainty
in Measurement-significant figures, dimensional analysis; Laws of Chemical
Combinations - Law of Conservation of Mass, Law of Definite Proportions, Law of
Multiple Proportions, Gay-Lussac’s
Law of Gaseous Volumes, Dalton’s Atomic Theory, Avogadro’s Law, Atomic and
molecular masses- mole concept and molar mass. Concept of equivalent weight;
Percentage composition of compounds and calculations of empirical and molecular
formulae of compounds; Stoichiometry and stoichiometric calculations; Methods
of expressing concentrations of solutions-mass percent, mole fraction,
molarity, molality and normality; Redox reactions-classical idea of redox
reactions, oxidation and reduction reactions-redox reactions in terms of
electron transfer; Oxidation number concept; Types of Redox reactionscombination,
decomposition, displacement and disproportionation reactions; Balancing of
redox reactions - oxidation number method Half reaction (ion-electron) method;
Redox reactions in Titrimetry.
7)
THERMODYNAMICS: Thermodynamic Terms;
The system and the surroundings; Types of systems and surroundings; The state
of the system; The Internal Energy as a State Function. (a) Work (b) Heat (c)
The general case, the first law of Thermodynamics; Applications; Work;
Enthalpy, H- a useful new state function; Extensive and intensive properties;
Heat capacity; The relationship between Cp and Cv; Measurement of U and
H: Calorimetry; Enthalpy change, rH of reactions - reaction
Enthalpy (a) Standard enthalpy of reactions, (b) Enthalpy changes during phase
transformations, (c) Standard enthalpy of formation, (d) Thermo chemical
equations (e) Hess’s law of constant heat summation; Enthalpies for different
types of reactions. (a) Standard enthalpy of combustion (∆cH),
(b) Enthalpy of atomization (∆aH), phase transition,
sublimation and ionization, (c) Bond Enthalpy (∆bondH ),
(d) Enthalpy of solution (∆solH) and dilution;
Spontaneity. (a) Is decrease in enthalpy a criterion for spontaneity? (b)
Entropy and spontaneity, the second law of thermodynamics, (c) Gibbs Energy and
spontaneity; Gibbs Energy change and equilibrium; Absolute entropy and the
third law of thermodynamics.
8)
CHEMICAL EQUILIBRIUM AND ACIDS-BASES:
Equilibrium in Physical processes; Equilibrium in chemical processes - Dynamic
Equilibrium; Law of chemical Equilibrium - Law of mass action and Equilibrium
constant; Homogeneous Equilibria, Equilibrium constant in gaseous systems. Relationship between KP and Kc;
Heterogeneous Equilibria; Applications of Equilibrium constant; Relationship
between Equilibrium constant K, reaction quotient Q and Gibbs energy G; Factors
affecting Equilibria.-Le Chatelier’s principle application to industrial
synthesis of Ammonia and Sulphur trioxide; Ionic Equilibrium in solutions;
Acids, bases and salts- Arrhenius, Bronsted-Lowry and Lewis concepts of acids
and bases; Ionisation of Acids and Bases -Ionisation constant of water and its
ionic product- pH scale-ionisation constants of weak acids-ionisation of weak
bases-relation between Ka and Kb-Di and poly basic acids
and di and poly acidic Bases-Factors affecting acid strength-Common ion effect
in the ionization of acids and bases-Hydrolysis of salts and pH of their
solutions; Buffer solutionsdesigning of buffer solution-Preparation of Acidic buffer;
Solubility Equilibria of sparingly soluble salts. Solubility product constant, Common ion
effect on solubility of ionic salts.
9)
HYDROGEN AND ITS COMPOUNDS: Position of
hydrogen in the periodic table; Dihydrogen-Occurrence and Isotopes; Preparation
and properties of Dihydrogen; Hydrides: Ionic, covalent, and non-stoichiometric
hydrides; Water: Physical properties; structure of water, ice. Chemical
properties of water; hard and soft water, Temporary and permanent hardness of
water; Hydrogen peroxide: Preparation; Physical properties; structure and
chemical properties; storage and uses; Heavy Water; Hydrogen as a fuel.
10)
THE s - BLOCK ELEMENTS (ALKALI AND
ALKALINE EARTH METALS)
Group 1 Elements : Alkali metals; Electronic configurations; Atomic and
Ionic radii;
Ionization enthalpy; Hydration enthalpy; Physical properties; Chemical
properties; Uses; General characteristics of the compounds of the alkali
metals: Oxides; Halides; Salts of oxo Acids; Anomalous properties of Lithium:
Differences and similarities with other alkali metals, Diagonal relationship;
similarities between Lithium and Magnesium; Some important compounds of Sodium:
Sodium Carbonate; Sodium Chloride; Sodium Hydroxide; Sodium hydrogen carbonate;
Biological importance of Sodium and Potassium.
Group 2 Elements: Alkaline earth elements; Electronic configuration;
Ionization enthalpy; Hydration enthalpy; Physical properties, Chemical
properties; Uses; General characteristics of compounds of the Alkaline Earth
Metals: Oxides, hydroxides, halides, salts of oxoacids (Carbonates; Sulphates
and Nitrates); Anomalous behavior of Beryllium; its diagonal relationship with
Aluminium; Some important compounds of calcium: Preparation and uses of Calcium
Oxide; Calcium Hydroxide; Calcium Carbonate; Plaster of Paris; Cement;
Biological importance of Calcium and Magnesium.
11)
p- BLOCK ELEMENTS GROUP 13 (BORON
FAMILY):
General introduction - Electronic configuration, Atomic radii,
Ionization enthalpy, Electro negativity; Physical & Chemical properties;
Important trends and anomalous properties of boron; Some important compounds of
boron - Borax, Ortho boric acid, diborane; Uses of boron, aluminium and their
compounds.
12)
p-BLOCK ELEMENTS - GROUP 14 (CARBON
FAMILY):
General introduction - Electronic configuration, Atomic radii,
Ionization enthalpy, Electro negativity; Physical & Chemical properties;
Important trends and anomalous properties of carbon; Allotropes of carbon; Uses
of carbon; Some important compounds of carbon and silicon – carbon monoxide,
carbon dioxide, Silica, silicones, silicates and zeolites.
13)
ENVIRONMENTAL CHEMISTRY:
Definition of terms: Air, Water and Soil Pollutions; Environmental
Pollution; Atmospheric pollution; Tropospheric Pollution; Gaseous Air
Pollutants (Oxides of Sulphur; Oxides of Nitrogen; Hydrocarbons; Oxides of
Carbon (CO, CO2)). Global warming and Greenhouse effect; Acid rain-
Particulate Pollutants- Smog; Stratospheric Pollution: Formation and breakdown
of Ozone- Ozone hole- effects of depletion of the Ozone Layer; Water Pollution:
Causes of Water Pollution; International standards for drinking water; Soil
Pollution: Pesticides, Industrial Wastes; Strategies to control environmental
pollution- waste Management- collection and disposal; Green Chemistry: Green
chemistry in day-to-day life;
Dry cleaning of clothes; Bleaching of paper; Synthesis of chemicals
14)
ORGANIC CHEMISTRY-SOME BASIC
PRINCIPLES, TECHNIQUES
AND HYDROCARBONS
SOME BASIC PRINCIPLES AND
TECHNIQUES
General introduction; Tetravalency of Carbon: shapes of organic
compounds; Structural representations of organic compounds; Classification of
organic compounds; Nomenclature of organic compounds; Isomerism; Fundamental
concepts in organic reaction mechanisms; Fission of covalent bond; Nucleophiles
and electrophiles; Electron movements in organic reactions; Electron
displacement effects in covalent bonds: inductive effect, resonance, resonance
effect, electromeric effect, hyperconjugation; Types of Organic Reactions;
Methods of purification of organic compounds; Qualitative elemental analysis of
organic compounds; Quantitative elemental analysis of organic compounds.
HYDROCARBONS
Classification of Hydrocarbons; Alkanes - Nomenclature, isomerism
(structural and conformations of ethane only); Preparation of alkanes;
Properties - Physical properties and chemical Reactivity, Substitution
reactions - Halogenation(free radical
mechanism), Combustion, Controlled Oxidation, Isomerisation, Aromatization,
reaction with steam and Pyrolysis; Alkenes- Nomenclature, structure of ethene,
Isomerism (structural and geometrical);
Methods of preparation; Properties- Physical and chemical reactions:
Addition of Hydrogen, halogen, water, sulphuric acid, Hydrogen halides
(Mechanism- ionic and peroxide effect, Markovnikov’s, anti-Markovnikov’s or
Kharasch effect). Oxidation, Ozonolysis and Polymerization; Alkynes -
Nomenclature and isomerism, structure of acetylene. Methods of preparation of
acetylene; Physical properties, Chemical reactions- acidic character of
acetylene, addition reactions- of hydrogen, Halogen, Hydrogen halides and
water. Polymerization; Aromatic Hydrocarbons: Nomenclature and isomerism,
Structure of benzene, Resonance and aromaticity; Preparation of benzene.
Physical properties. Chemical properties: Mechanism of electrophilic
substitution. Electrophilic substitution reactions- Nitration, Sulphonation,
Halogenation, Friedel-Crafts alkylation and acylation; Directive influence of
functional groups in mono substituted benzene, Carcinogenicity and
toxicity
14) SOLID STATE:
General characteristics of solid state; Amorphous and crystalline solids; Classification of crystalline solids based on different binding forces (molecular, ionic, metallic and covalent solids); Probing the structure of solids: X-ray crystallography; Crystal lattices and unit cells. Number of atoms in a unit cell (primitive, body centred and face centred cubic unit cell); Close packed structures: Close packing in one dimension, in two dimensions and in three dimensions- tetrahedral and octahedral voids- formula of a compound and number of voids filled-locating tetrahedral and octahedral voids; Packing efficiency in simple cubic, bcc and in hcp, ccp lattice; Calculations involving unit cell dimensions-density of the unit cell; Imperfections in solids-types of point defects-stoichiometric and non-stoichiometric defects.
15) SOLUTIONS:
Types of solutions; Expressing concentration of solutions - mass
percentage, volume percentage, mass by volume percentage, parts per
million, mole fraction,
molarity and molality; Solubility: Solubility of a solid
in a liquid, solubility of a gas in a liquid, Henry’s law; Vapour pressure of
liquid solutions: vapour pressure of liquid- liquid solutions. Raoult’s
law as a special case of Henry’s law
-vapour pressure of solutions of solids in liquids; Ideal and non-ideal solutions; Colligative properties
and determination of molar mass-relative lowering of vapour
pressure-elevation of boiling point-depression of freezing point-osmosis and
osmotic pressure-reverse osmosis
and water purification.
16) ELECTROCHEMISTRY AND CHEMICAL KINETICS:
ELECTROCHEMISTRY:
Nernst equation-equilibrium constant from Nernst equation - electro
chemical cell and Gibbs energy of the cell reaction; Conductance of
electrolytic solutions - measurement of the conductivity of ionic
solutions-variation of conductivity and molar
conductivity with concentration-strong electrolytes
and weak electrolytes-applications of Kohlrausch’s law; Electrolysis: Faraday’s
laws of electrolysis-products of electrolysis.
CHEMICAL KINETICS: Rate of a chemical reaction; Factors influencing rate
of a reaction: dependance of rate on
concentration- rate expression and rate constant- order of a reaction,
molecularity of a reaction; Integrated rate equations-zero order reactions-first
order
reactions - half life of a reaction; Pseudo first order reaction; Temperature dependence of the rate
of a reaction - Effect of catalyst.
17) SURFACE CHEMISTRY: Adsorption and absorption: Distinction between adsorption and absorption-mechanism of adsorption-types of adsorption-characteristics of
physisorptioncharacteristics of chemisorption-adsorption isotherms-adsorption
from solution phaseapplications of adsorption.
Colloids; Classification of colloids: Classification based on physical
state of dispersed phase and dispersion medium- classification based on nature
of interaction between dispersed phase and dispersion medium- classification
based on type of particles of the dispersed phase- multi molecular, macromolecular
and associated colloids- cleansing
action of soaps-preparation of
colloids-purification of
colloidal solutions- properties of colloidal solutions: Tyndal effect,
colour, Brownian movement-charge on colloidal particles, electrophoresis. Coagulation
or precipitation, Coagulation of lyophilic sols, protection of colloids,
Colloids around us, Applications of colloids.
18) p-BLOCK ELEMENTS:
GROUP-15 ELEMENTS: Occurrence- electronic configuration, atomic and
ionic radii, ionisation enthalpy, electronegativity, physical and chemical properties; Dinitrogenpreparation,
properties and uses; Compounds of nitrogen-preparation, properties and uses of
ammonia; Oxides of nitrogen; Preparation and properties and uses of nitric
acid; Phosphorousallotropic forms;
GROUP-16 ELEMENTS: Occurrence- electronic configuration, atomic and
ionic radii, ionisation enthalpy, electron gain enthalpy, electronegativity,
physical and chemical
properties; Dioxygen-preparation, properties and uses; Simple oxides;
Ozone-preparation, properties, structure and uses; Sulphur-allotropic forms; Sulphur dioxide-preparation, properties and uses;
Oxoacids of sulphur; Sulphuric acid- properties and uses only.
GROUP-17 ELEMENTS: Occurrence, electronic configuration, atomic and
ionic radii, ionisation enthalpy, electron gain enthalpy, electronegativity,
physical and chemical properties; Chlorine- preparation, properties and uses;
Hydrogen chloride- preparation, properties and uses; Oxoacids of halogens; Interhalogen compounds.
GROUP-18 ELEMENTS: Occurrence, electronic configuration, ionization
enthalpy, atomic radii, electron gain
enthalpy, physical and chemical properties(a)
Xenon-fluorine compounds - XeF2,
XeF4 and XeF6
-preparation, hydrolysis and formation
of fluoro anions-structures
of XeF2, XeF4 and XeF6 (b) Xenon-oxygen compounds XeO3 and XeOF4 - their formation and structures. Uses.
19) d AND f
BLOCK ELEMENTS & COORDINATION COMPOUNDS:
d AND f BLOCK ELEMENTS :Position in the periodic table; Electronic
configuration of the d-block elements; General properties of the transition
elements (d-block) -physical properties, variation in atomic and ionic sizes
of transition series, ionisation enthalpies, oxidation states,
trends in the M²+/M and M³+/M²+ standard
electrode potentials, trends in stability of higher oxidation states,
chemical reactivity and Eθ values,
magnetic properties, formation
of coloured ions, formation
of complex compounds, catalytic
properties, formation of interstitial compounds, alloy formation.
COORDINATION COMPOUNDS: Werner’s theory of coordination compounds;
Definitions of some terms
used in coordination compounds; Nomenclature of coordination
compounds-IUPAC nomenclature; Isomerism in coordination compounds- (a)Stereo
isomerism-Geometrical and optical isomerism (b)Structural isomerism-linkage,
coordination, ionisation and hydrate isomerism; Bonding in coordination
compounds. (a)Valence bond theory -
magnetic properties of coordination compounds-limitations of valence bond theory (b)
Crystal field theory (i) Crystal field splitting in octahedral and tetrahedral coordination
entities (ii) Colour in coordination compounds-limitations of crystal field theory; Bonding in metal carbonyls;
Stability of coordination compounds; Importance and
applications of coordination
compounds.
20)
BIOMOLECULES: Carbohydrates-
Classification of carbohydrates-Monosaccharides: preparation
of glucose from sucrose
and starch- Properties and structure of glucose - D, L and (+),
(-) configurations of glucose- Structure of fructose.
Amino acids: Natural amino acids
- classification of amino acids - structures and D and L
forms-Zwitterions; Proteins: Structures, classification, fibrous and globular-
primary, secondary, tertiary and quaternary structures of proteins-
Denaturation of proteins.
Nucleic acids: chemical composition of nucleic acids, structures of nucleic
acids, DNA finger
printing, biological functions
of nucleic acids.
21)
HALOALKANES AND HALOARENES:
Classification and nomenclature; Nature of
C-X bond; Methods of preparation:
Alkyl halides and
aryl halides-from alcohols, from
hydrocarbons (a) by free radical halogenation (b) by electrophilic substitution (c) by
replacement of diazonium group (Sandmeyer reaction) (d) by the addition of hydrogen halides
and halogens to
alkenes-by halogen exchange
(Finkelstein reaction); Physical properties-melting and boiling points, density
and solubility; Chemical reactions: Reactions of haloalkanes (i) Nucleophilic substitution reactions (a)
SN² mechanism (b) SN¹ mechanism (c) stereochemical aspects of nucleophilic
substitution reactions-optical activity (ii)
Elimination reactions (iii) Reaction
with metals-Reactions of haloarenes: (i) Nucleophilic substitution (ii)Electrophilic substitution and (iii) Reaction with
metals.
22)
ORGANIC COMPOUNDS CONTAINING C, H AND O
(Alcohols, Phenols, Ethers, Aldehydes,
Ketones and Carboxylic acids):
ALCOHOLS, PHENOLS AND ETHERS
Alcohols, phenols and ethers -
classification; Nomenclature: (a)Alcohols, (b)phenols and (c) ethers; Structures of
hydroxy and ether
functional groups; Methods of
preparation: Alcohols from alkenes and carbonyl compounds (reduction and
reaction with Grignard reagents); Phenols from haloarenes, benzene sulphonic
acid, diazonium salts, cumene; Physical properties of alcohols and
phenols; Chemical reactions
of alcohols and
phenols (i) Reactions involving cleavage of O-H bond-Acidity of alcohols
and phenols, esterification (ii)
Reactions involving cleavage of C-O bond -
reactions with HX, PX3, dehydration
and oxidation (iii) Reactions of phenols - electrophilic
aromatic substitution, Kolbe’s reaction,
Reimer - Tiemann
reaction, reaction with zinc
dust, oxidation.
Ethers-Methods of preparation: By dehydration of alcohols, Williamson synthesis - Physical Properties - Chemical reactions: Cleavage of C-O bond and electrophilic substitution of aromatic ethers.
ALDEHYDES AND KETONES
Nomenclature and structure
of carbonyl group; Preparation of aldehydes and ketones(1) by oxidation of alcohols (2) by
dehydrogenation of alcohols (3) from hydrocarbons Preparation of aldehydes
(1) from acyl chlorides (2) from nitriles and esters (3) from
hydrocarbons-Preparation of ketones (1)
from acyl chlorides (2) from nitriles (3) from benzene or substituted
benzenes; Physical properties of
aldehydes and ketones; Chemical reactions of aldehydes and ketones-nucleophilic
addition, reduction, oxidation, reactions due to alpha Hydrogen and other reactions (Cannizzaro
reaction, electrophilic substitution reaction); Uses of aldehydes and
ketones.
CARBOXYLIC ACIDS
Nomenclature and structure
of carboxyl group; Methods of
preparation of carboxylic
acids (1)from primary
alcohols and aldehydes
(2) from alkylbenzenes(3)from nitriles
and amides (4)from Grignard reagents (5) from acyl halides and
anhydrides (6) from esters; Physical properties; Chemical reactions: (i) Reactions
involving cleavage of O-H bond-acidity, reactions with metals and alkalies (ii)
Reactions involving cleavage of
C-OH bond-formation of
anhydride, reactions with PCl5, PCl3, SOCl2,
esterification and reaction with ammonia
(iii) Reactions involving-COOH group-reduction, decarboxylation (iv)
Substitution reactions in
the hydrocarbon part - halogenation
and ring substitution; Uses of carboxylic acids.
23) ORGANIC COMPOUNDS CONTAINING NITROGEN:
AMINES
Structure of amines; Classification; Nomenclature; Preparation of
amines: reduction of nitro
compounds, ammonolysis of alkyl halides, reduction of nitriles, reduction
of amides, Gabriel phthalimide synthesis and Hoffmann bromamide
degradation reaction; Physical
properties; Chemical reactions: basic character of amines, alkylation,
acylation, carbyl amine reaction,
reaction with nitrous
acid, reaction with
aryl sulphonyl chloride, electrophilic substitution of aromatic
amines-bromination, nitration and Sulphonation.
1st Year Deleted Syllabus
|
Name of the Chapter |
Deleted sub topics |
|
Atomic Structure |
1.1 Sub-atomic particles:(Discovery
of Election, proton and Neutron); atomic number,
isotopes and isobars. 1.2 Atomic Model: Thomson’s
model and its limitations. Rutherford’s
model and its limitations 1.6 Quantum mechanical model of an atom - shapes of atomic
orbitals |
|
Classification of Elements and Periodicity in Properties |
2.1 Need to classify elements 2.2 Genesis of periodic classification. |
|
Chemical Bonding and Molecular Structure |
----------Nil--------- |
|
States of Matter: Gases
and Liquids |
4.10 Distribution of
molecular speeds – rms, average and
most probable speeds- kinetic
energy of gas molecules 4.12 Liquefaction of gases 4.13 Liquid
state – properties of liquids in terms
of intermolecular interactions- vapour pressure, surface tension and viscosity (Qualitative idea only. No mathematical
derivation) |
|
Stoichiometry |
5.2 Laws of chemical combinations, Gay Lussac’s law of gaseous volumes, Dalton’s atomic theory,
Avogadro law 5.6 methods of
expressing concentration of solutions 5.11 redox reactions in titrimetry.(Applications of redox reactions) |
|
Thermodynamics |
6.2.4Heat capacity and specific heat
capacity 6.7 Criteria
for equilibrium |
|
Chemical Equilibrium and Acids and Bases |
7.7 Relationship between equilibrium
constant K, reaction quotient Q and Gibbs energy G 7.11 Ionisation of acids and bases 7.12 Henderson equation derivation |
|
Hydrogen and its Compounds |
8.3 Preparation of dihydrogen 8.4 Properties of dihydrogen 8.7 Hydrogen peroxide preparation and
properties, structure and use) |
|
s-Block Elements: Alkali and
Alkaline Earth Metals |
9.4 Some important compounds of
sodium:sodiumcarbonate; sodium
chloride; sodium hydroxide; sodium hydrogen carbonate 9.5 Biological importance of sodium and
potassium Group 2 elements 9.9 Some important compounds of calcium 9.10
Biological
importance of magnesium and Calcium. |
|
p-Block Elements : Group-13
Boron Family |
10.3 Important compounds of boron – borax,
orthoboric acid, diboran 10.4 Uses of boron, aluminium and their
compound. |
|
p-Block Elements : Group-14
Carbon Family |
11.4 Some important compounds of carbon
and silicon, carbon monoxide, carbon dioxide, silicon dioxide, silicones,
silicates and zeolites. |
|
Environmental Chemistry |
ENTIRE CHAPTER DELETED |
|
Organic Chemistry : Some Basic Principles and Techniques
Hydrocarbons |
13.8 Methods of purification of organic
compounds 13.9 Qualitative elemental analysis of
organic compounds 13.10 Quantitative elemental analysis of
organic compounds. Note: Free radical mechanism of halogenations, combustion and
pyrolysis |
2nd Year Deleted Syllabus
Chapter
1 Solid state
1.11
Electrical properties
1.12
Magnetic properties (Band theory of metals, conductors, semiconductors and
insulators and n and p type semiconductors)
Chapter
2 Solutions
2.7
Abnormal molar masses-Van’t Hoff factor.
Chapter
3 Electrochemistry and Chemical Kinetics
Electrochemistry
3.1
Electrochemical cells
3.2
Galvanic cells
3.5
Electrolytic cells
3.6
Batteries: primary and secondary batteries
3.7
Fuel cells
3.8
Corrosion of metals-Hydrogen economy
Chemical
kinetics
3.14
Collision theory of chemical reaction rates.
Chapter
4 Surface Chemistry
4.2
catalysis, homogenous and heterogenous, Adsorption theory of heterogenous
catalysis, activity and selectivity of
solid catalysis, Shape-selective catalysis by zeolites, Enzyme catalysis,
Catalysts in industry.
4.5 Emulsions – types of emulsions
Chapter 5 General
Principles of Metallurgy Entire
chapter is deleted
Chapter
6 P-block Elements
Group-15
Elements
6.7
Phosphine-preparation, properties and uses
6.8
Phosphorous halides
6.9
Oxoacids of phosphorous
Group
-16 Elements
6.17
Sulphuric acid-manufacture.
Chapter 7 d and f Block Elements & Coordination
Compounds d and f Block Elements
7.4
Some important compounds of transition elements
7.5
Inner transition elements
7.6
Actinoids
7.7
Some applications of d and f block elements.
Chapter
8 Polymers
Entire
chapter is deleted
Chapter
9 Biomolecules
9.1
Disaccharides (sucrose, lactose, maltose), polysaccharides (starch, cellulose,
glycogen), importance of carbohydrates.
9.3
Enzymes: Enzymes, mechanism of enzyme action
9.4
Vitamins 9.6 Hormones.
Chapter 10 Chemistry in
Everyday life Entire chapter is deleted
Chapter
11 Halo Alkanes and Halo Arenes
11.6
Polyhalogeno compounds.
Chapter
12 Organic Compounds Containing C, H and O
12.7
Some Commercially important alcohols (uses with special reference to methanol
and ethanol)
Chapter
13 Organic Compounds Containing Nitrogen
II.
Diazonium salts
13.7
Methods of preparation of diazonium salts
13.8
Physical properties
13.9
Chemical reactions
13.10 Importance
of diazonium salts in synthesis of aromatic compounds
III.
Cyanides and Isocyanides
13.11 Structure
and nomenclature of cyanides and isocyanides
13.12 Preparation,
physical properties and chemical reactions of cyanides and isocyanides.
